Design and Control of Highly Conductive Single-Molecule Junctions (Запис № 446807)

МАРК-запис
000 -LEADER
fixed length control field 05346nam a22006735i 4500
001 - CONTROL NUMBER
control field 978-981-10-4412-0
003 - CONTROL NUMBER IDENTIFIER
control field DE-He213
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20210118125039.0
007 - PHYSICAL DESCRIPTION FIXED FIELD--GENERAL INFORMATION
fixed length control field cr nn 008mamaa
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 170405s2017 si | s |||| 0|eng d
020 ## - INTERNATIONAL STANDARD BOOK NUMBER
International Standard Book Number 9789811044120
-- 978-981-10-4412-0
024 7# - OTHER STANDARD IDENTIFIER
Standard number or code 10.1007/978-981-10-4412-0
Source of number or code doi
050 #4 - LIBRARY OF CONGRESS CALL NUMBER
Classification number QD450-882
072 #7 - SUBJECT CATEGORY CODE
Subject category code PNR
Source bicssc
072 #7 - SUBJECT CATEGORY CODE
Subject category code SCI013050
Source bisacsh
072 #7 - SUBJECT CATEGORY CODE
Subject category code PNR
Source thema
082 04 - DEWEY DECIMAL CLASSIFICATION NUMBER
Classification number 541
Edition number 23
100 1# - MAIN ENTRY--PERSONAL NAME
Personal name Kaneko, Satoshi.
Relator term author.
Relator code aut
-- http://id.loc.gov/vocabulary/relators/aut
245 10 - TITLE STATEMENT
Title Design and Control of Highly Conductive Single-Molecule Junctions
Medium [electronic resource] :
Remainder of title A Focus on the Metal–Molecule Interface /
Statement of responsibility, etc by Satoshi Kaneko.
250 ## - EDITION STATEMENT
Edition statement 1st ed. 2017.
264 #1 -
-- Singapore :
-- Springer Singapore :
-- Imprint: Springer,
-- 2017.
300 ## - PHYSICAL DESCRIPTION
Extent XIII, 84 p. 40 illus., 38 illus. in color.
Other physical details online resource.
336 ## -
-- text
-- txt
-- rdacontent
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-- computer
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-- rdamedia
338 ## -
-- online resource
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347 ## -
-- text file
-- PDF
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490 1# - SERIES STATEMENT
Series statement Springer Theses, Recognizing Outstanding Ph.D. Research,
Міжнародний стандартний серійний номер для назви серії (ISSN) 2190-5053
505 0# - FORMATTED CONTENTS NOTE
Formatted contents note Introduction -- Theoretical background -- Experimental concepts and techniques -- Design of the metal–molecule interaction at the benzene single-molecule junction -- Design of the interface structure of a single-molecule junction utilizing spherical endohedral Ce@C82 metallofullerenes -- Anchoring groups enclosed in the π-conjugated system in N2 molecules -- Controlling the electrical property of highly conductive pyrazine single-molecule junction -- General conclusions.
520 ## - SUMMARY, ETC.
Summary, etc This thesis describes improvements to and control of the electrical conductance in single-molecule junctions (SMJs), which have potential applications in molecular electronics, with a focus on the bonding between the metal and molecule. In order to improve the electrical conductance, the π orbital of the molecule is directly bonded to the metal orbital, because anchoring groups, which were typically used in other studies to bind molecule with metal electrodes, became resistive spacers. Using this direct π-binding, the author has successfully demonstrated highly conductive SMJs involving benzene, endohedral metallofullerene Ce@C82, and nitrogen. Subsequently, the author investigated control of the electrical conductance of SMJs using pyrazine. The nitrogen atom in the π-conjugated system of pyrazine was expected to function as an anchoring point, and two bonding states were expected. One originates primarily from the π orbital, while the other originates primarily from an n state of the nitrogen. Measurements of conductance and dI/dV spectra coupled with theoretical calculations revealed that the pyrazine SMJ has bistable conductance states, in which the pyrazine axis is either tilted or parallel with respect to the junction axis. The bistable states were switched by changing the gap size between the metal electrodes using an external force. Notably, it is difficult to change the electrical properties of bulk-state materials using mechanical force. The findings reveal that the electron transport properties of a SMJ can be controlled by designing a proper metal–molecule interface, which has considerable potential for molecular electronics. Moreover, this thesis will serve as a guideline for every step of SMJ research: design, fabrication, evaluation, and control.
506 ## - RESTRICTIONS ON ACCESS NOTE
Terms governing access Available to subscribing member institutions only. Доступно лише організаціям членам підписки.
506 ## - RESTRICTIONS ON ACCESS NOTE
Standardized terminology for access restriction Online access from local network of NaUOA.
506 ## - RESTRICTIONS ON ACCESS NOTE
Standardized terminology for access restriction Online access with authorization at https://link.springer.com/
506 ## - RESTRICTIONS ON ACCESS NOTE
Standardized terminology for access restriction Онлайн-доступ з локальної мережі НаУОА.
506 ## - RESTRICTIONS ON ACCESS NOTE
Standardized terminology for access restriction Онлайн доступ з авторизацією на https://link.springer.com/
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Physical chemistry.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanoscale science.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanoscience.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanostructures.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanotechnology.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanochemistry.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Electronics.
650 #0 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Microelectronics.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Physical Chemistry.
-- http://scigraph.springernature.com/things/product-market-codes/C21001
650 24 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanoscale Science and Technology.
-- http://scigraph.springernature.com/things/product-market-codes/P25140
650 24 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanotechnology.
-- http://scigraph.springernature.com/things/product-market-codes/Z14000
650 24 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Nanochemistry.
-- http://scigraph.springernature.com/things/product-market-codes/C33000
650 24 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name as entry element Electronics and Microelectronics, Instrumentation.
-- http://scigraph.springernature.com/things/product-market-codes/T24027
710 2# - ADDED ENTRY--CORPORATE NAME
Corporate name or jurisdiction name as entry element SpringerLink (Online service)
773 0# - HOST ITEM ENTRY
Title Springer eBooks
776 08 - ADDITIONAL PHYSICAL FORM ENTRY
Display text Printed edition:
International Standard Book Number 9789811044113
776 08 - ADDITIONAL PHYSICAL FORM ENTRY
Display text Printed edition:
International Standard Book Number 9789811044137
776 08 - ADDITIONAL PHYSICAL FORM ENTRY
Display text Printed edition:
International Standard Book Number 9789811351297
830 #0 - SERIES ADDED ENTRY--UNIFORM TITLE
Uniform title Springer Theses, Recognizing Outstanding Ph.D. Research,
-- 2190-5053
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://doi.org/10.1007/978-981-10-4412-0">https://doi.org/10.1007/978-981-10-4412-0</a>
912 ## -
-- ZDB-2-CMS
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type ЕКнига

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