TY - BOOK AU - Dickerson R. E. AU - Gray H.B. AU - Haight G.P. TI - Chemical Principles PY - 1974/// CY - Menlo Park, California, Reading, Massachusetts, London, Amsterdam PB - W. A. Benjamin, Inc. KW - 54 Хімія. Кристалографія. Мінералогія N2 - Main topics covered in "Chemical Principles" (Dickerson, Gray, Haight) - Introduction to General Chemistry -- Atomic structure, electron configuration -- Periodic law and trends in the periodic table -Chemical Bonds and Molecular Structure -- Ionic, covalent, and metallic bonding -- Molecular geometry, valence theories, and molecular orientation -- Structure determination methods: VSEPR, orbital diagrams - Chemical Reactions and Stoichiometry -- Law of conservation of mass, balancing equations -- Types of reactions: exchange, redox, acid–base -- Solutions and solubility, colloidal systems - Thermochemistry -- First and second laws of thermodynamics -- Enthalpy, enthalpy change, entropy, Gibbs free energy -- Heat balance of reactions and electrochemistry (often covered) - Chemical Equilibrium and Dynamics -- Chemical equilibrium, rate constant -- Law of mass action, Le Châtelier's principle - Chemical Kinetics -- Reaction rates, temperature dependence (Arrhenius equation) -- Mechanisms and transition-state theory - Atomic and Molecular Spectroscopy -- Principles of absorption, emission, and scattering of light -- Basic concepts of electronic, rotational, and vibrational spectroscopy - Thermodynamics of Chemical Systems -- Roles of enthalpy, entropy, and free energy in predicting reaction direction -- Thermodynamic rationales with solvents and gases - Chemistry of Solutions -- Concentrations, solution calculations, buffer systems -- Electrolyte solutions and their properties - Gas Chemistry and States of Matter -- Ideal gas law, deviations for real gases -- Equations of state and their applications - Electrochemistry and Charge Transfer -- Electrochemical cells, cell potentials -- Electrolysis and charge transport in solutions - Materials Chemistry and Biochemical Contexts (as needed) -- Basics of materials chemistry, interactions with biological systems ER -