TY  - BOOK
AU  - Imoto,Kenta
ED  - SpringerLink (Online service)
TI  - Multifunctional Molecular Magnets Based on Octacyanidometalates
T2  - Springer Theses, Recognizing Outstanding Ph.D. Research,
SN  - 9789811061356
AV  - QD146-197 
U1  - 546 23
PY  - 2017///
CY  - Singapore
PB  - Springer Singapore, Imprint: Springer
KW  - Inorganic chemistry
KW  - Magnetism
KW  - Magnetic materials
KW  - Optical materials
KW  - Electronic materials
KW  - Physical chemistry
KW  - Inorganic Chemistry
KW  - Magnetism, Magnetic Materials
KW  - Optical and Electronic Materials
KW  - Physical Chemistry
N1  - 1. Introduction -- 2. Light-induced Spin-crossover Magnetism in an Iron Octacyanidoniobate-based Assembly -- 3. Two-step Spin-crossover and Photo-induced Spin-crossover in an Iron Octacyanidoniobate-based Assembly -- 4. Observation of Coexistence of Super-ionic Conductivity and Metamagnetism in a Manganese Octacyanidoniobate-based Assembly -- 5. Summary and Perspective; Available to subscribing member institutions only. Доступно лише організаціям членам підписки
N2  - This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices
UR  - https://doi.org/10.1007/978-981-10-6135-6
ER  -